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Write a balanced redox reaction between acidified potassium permanganate and iron two chloride and predict if the reaction is spontaneous Emno.4/Mn^2+=1.74v fe^2+|fe^3+=0.75

Respuesta :

The balanced redox reaction between acidified potassium and iron two chloride is given as ,

5[tex]Fe^{+2}[/tex] + 1 [tex]MnO_{4} ^{- }[/tex] + 8 [tex]H^{+}[/tex]→ 5[tex]Fe^{+3}[/tex] ++ 1 [tex]Mn^{+2 }[/tex] + 4[tex]H_{2} O[/tex]

The reaction is spontaneous

Place these numbers as coefficients in front of the formulas containing those atoms.

[tex]Fe^{+2}[/tex] +  [tex]MnO_{4} ^{- }[/tex] → [tex]Fe^{+3}[/tex] + [tex]Mn^{+2 }[/tex]

Balance all remaining atoms other than H and O

[tex]Fe^{+2}[/tex] +  [tex]MnO_{4} ^{- }[/tex] → [tex]Fe^{+3}[/tex] + [tex]Mn^{+2 }[/tex]

Balance O.

Add enough H2O molecules to the deficient side to balance O.

We have 4O atoms on the left, so we need 4H2O

on the right.

5[tex]Fe^{+2}[/tex] + 1 [tex]MnO_{4} ^{- }[/tex] + 8 [tex]H^{+}[/tex]→ 5[tex]Fe^{+3}[/tex] + 1 [tex]Mn^{+2 }[/tex] + 4[tex]H_{2} O[/tex]

The reaction is spontaneous when the value of E ° for the reaction is positive .

E ° for  [tex]MnO_{4} ^{- }[/tex]/   [tex]Mn^{+2 }[/tex] = 1.74 V

E ° = [tex]Fe^{+3}[/tex]/ [tex]Fe^{+2}[/tex] = 0.75 V

E ° for reaction = 1.74 V -  0.75 V = 0.99 V

Hence , E ° for reaction is positive .

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