Cl- ion is bigger than Na+ ion because of the presence of more number of electrons.
The atomic number of sodium+ ion is 10 means it has 10 number of electrons which can accommodate into 2 shells or orbits while on the hand, chlorine- ion has atomic number 18 means it has 18 number of electrons which can be accommodate into 3 shells or orbit.
So there is one shell more in chlorine ion as compared to sodium ion which make the size of chlorine ion large so we can conclude that chlorine ion is bigger than sodium ion.
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