The freezing point of benzene is 5.5°C. What is the freezing point of a solution of 2.60 g of naphthalene (C10H8) in 675 g of benzene (Kf of benzene = 4.90°C/m)?

Respuesta :

Answer: The freezing point of solution is 5.35°C

Explanation:

The equation used to calculate depression in freezing point follows:

[tex]\Delta T_f=\text{Freezing point of pure solution}-\text{Freezing point of solution}[/tex]

To calculate the depression in freezing point, we use the equation:

[tex]\Delta T_f=iK_fm[/tex]

Or,

[tex]\text{Freezing point of pure solution}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}[/tex]

where,

Freezing point of pure solution = 5.5°C

i = Vant hoff factor = 1 (For non-electrolytes)

[tex]K_f[/tex] = molal freezing point elevation constant = 4.90°C/m

[tex]m_{solute}[/tex] = Given mass of solute (naphthalene) = 2.60 g

[tex]M_{solute}[/tex] = Molar mass of solute (naphthalene) = 128.2 g/mol

[tex]W_{solvent}[/tex] = Mass of solvent (benzene) = 675 g

Putting values in above equation, we get:

[tex]5.5-\text{Freezing point of solution}=1\times 4.90^oC/m\times \frac{2.60\times 1000}{128.2g/mol\times 675}\\\\\text{Freezing point of solution}=5.35^oC[/tex]

Hence, the freezing point of solution is 5.35°C