∠QUR=139°
Because ∠QUR+∠SUR=180°(they are adjacent)
That could be even the anser on the first question. They are adjacent because SQ - is a line and UR - is the same ray.
A pair of a cute vertical angle:
∠TUP and ∠RUN vecause TN and RP are lines.
Name a pair of supplementary angles:
∠SUR and ∠RUN because ∠SUN = 90°
